Improved Drinking Water Disinfection with UVC-LEDs for Escherichia Coli and Bacillus Subtilis Utilizing Quartz Tubes as Light Guide

A new approach is investigated utilizing light guidance capabilities of optical pure quartz glass in order to maximize drinking water disinfection efficiency with UVC-light-emitting diodes (LEDs). Two experimental setups consisting of soda-lime AR® glass (VWR, Darmstadt, Germany) or HSQ® 100 quartz glass (Heraeus, Wasserburg, Germany) reactors were designed to compare disinfection rates with and without total reflection of UVC radiation along the reactor walls. Each reactor was filled with 9 mL bacteria samples containing either E. coli DSM (Deutsche Sammlung von Mikroorganismen) 498 or B. subtilis DSM 402 strains (concentration 1–3 × 106 colony forming units (CFU)/mL) with and without additional mixing and irradiation periods of 10, 40, and 90 s. Disinfection rates were increased up to 0.95 log10 (E. coli) and 0.75 log10 (B. subtilis) by the light guide approach in stagnant samples. The same experiments with mixing of the samples resulted in an increased disinfection efficiency of 3.07 log10 (E. coli) and 1.59 log10 (B. subtilis). Optical calculations determine that total reflection is achieved with the applied UVC-LED’s viewing angle of 15°. Furthermore measurements show that HSQ® 100 quartz has a transmittance of 92% at 280 nm UVC irradiation compared to the transmittance of soda-lime glass of 2% (1 mm wall thickness).